Product ID:S03702 BLAZE ORANGE, QUIK-MARK INVERTED (SUPP DATA)
MSDS Date:09/01/1996
FSC:8040
NIIN:00N081683
MSDS Number: CFSVZ

SHERWIN-WILLIAMS

31500 SOLON RD
SOLON, OH 44139
US

Emergency Phone: 216-566-2917

Info Phone: 800-777-2966; 800-247-3266

Cage: DO642

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

760.

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 14%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT

760.

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 6%

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

127.

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 13%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

250.

CAS: 107-83-5

RTECS: SA2985000

Fraction By Weight: 11%

OSHA PEL SEE INGREDIENT

ACGIH TLV: SEE INGREDIENT

300 PPM; 400 PPM (MFR).

CAS: 64742-89-8

Fraction By Weight: 8%

OSHA PEL SEE INGREDIENT

ACGIH TLV: 300 PPM (MFR)

22.

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SILICA, CRYSTALLINE - QUARTZ; (QUARTZ)

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 18%

OSHA PEL 0.1 MG/M3 (MFR)

ACGIH TLV: 0.1 MG/M3 RDUST

BARIUM SULFATE

CAS: 7727-43-7

RTECS: CR0600000

Fraction By Weight: 7%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST

BARIUM (SARA 313)

CAS: 7440-39-3

RTECS: CQ8370000

Fraction By Weight: 3.9%

OSHA PEL 0.5 MG/M3

ACGIH TLV: N/K

OVEREXP TO DECOMP PRODS MAY CAUSE HEALTH HAZARD.

RTECS: 9999999ZZ

PRLNG OVEREXP TO SOLV INGS MAY CAUSE

RTECS: 9999999ZZ

SYS. RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO SOLVS

RTECS: 9999999ZZ

DELIB CONC & INHALING CONTENTS CAN BE HARMFUL/FATAL.

RTECS: 9999999ZZ

OF CALIFORNIA TO CAUSE CANCER & BIRTH DEFECTS &

RTECS: 9999999ZZ

NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK

RTECS: 9999999ZZ

HAZARD LIST INFORMATION & SAFE HANDLING & EXPOSURE

RTECS: 9999999ZZ

UNDER PRESS. DO NOT PUNCTURE, INCIN/EXPOS TO

RTECS: 9999999ZZ

WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO

RTECS: 9999999ZZ

CHILDREN. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP &

RTECS: 9999999ZZ

MAY CONTAIN MATLS CLASSIFIED AS NUISANCE

RTECS: 9999999ZZ

SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS

RTECS: 9999999ZZ

ACGIH TLV 10 MG/M3 (TDUST), 3 MG/M3 (RESPIRABLE

RTECS: 9999999ZZ

FRACTION). ADDN OF REDUCERS/OTHER ADDITIVES TO THESE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR
PROPER USE, VENT & PPE. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY
CAUSE NERV SYS DEPRESS. EXTREME OV EREXP MAY RSLT IN UNCON & POSS
DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF
EXCESSIVE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, VOL 68, 1997:GRP 1. NTP 7TH ANNUAL RPT ON CARCINS,
1994:ANTIC TO BE CARCIN.
Effects of Overexposure:HLTH HAZ:EXPOS TO VAPS/SPRAY MISTS. REDNESS &
ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS.
CHRONIC:PRLNG & RPTD EXPOS TO HEXANE MAY CAUSE DMG TO NERVE TISS OF
ARMS & LEGS(PERIPHERAL N EUROPATHY), RSLTG IN MUSCULAR WEAK & LOSS
OF SENSATION. THIS EFT MAY BE INCR BY PRESENCE OF METHYL ETHYL
KETONE.(ING 12)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO
NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL
ATTENTION.

Flash Point Method:PMCC
Flash Point:<0F,<-18C
Lower Limits:0.9%
Upper Limits:27%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. CLSD CNTNRS MAY EXPLODE
(DUE TO BUILD-UP OF PRESS) WHEN EXPOS TO EXTREME HEAT. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS & OPEN FLAME. (SUPP DATA)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMM. KEEP
AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL ACCUM READILY & MAY
IGNITE EXPLOSIVELY. CONSULT NFPA CODE.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA
VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS;
TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF
IGNIT. USE APPRVD BONDIN G & GROUNDING PROCS. CONTENTS (ING 18)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED NIOSH APPRVD ORG
VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING
DRIED FILM, WEAR NIOSH APPRV D DUST/MIST RESP FOR DUST WHICH
(SUPDAT)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS
MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (SUPP DATA)
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:MARKING PAINTS - 3. FIRE FIGHT PROC:PVNT PRESS
BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. RESP
PROT:MAY BE GENERATED FROM THIS PROD, UNDERLYING PAINT/ABRASIVE .
VENT:1910.94, 1910.107, 1910.108. EXPLO HAZ:APPLICATION TO HOT
SURFS REQS SPECIAL PRECS. DURING EMER CNDTNS (ING 11)

Boiling Pt:B.P. Text:<395F,<202C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.77-0.95
VOC Grams/Liter:4.51
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THESE PRODS MAY BE HAZ AS DEFINED
UNDER THE RCRA (40 CFR 261). WASTE MUST BE TESTED FOR IGNITABILITY
TO DETERMINE APPLIC EPA HAZ WASTE NUMBERS. DO NOT INCIN.
DEPRESSURIZE CNTNR. DISP OF I/A /W FED, STATE & LOCAL REGS
REGARDING POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.